These hot oil droplets can bounce off any surface

The Hong Kong physicists were interested in hot droplets striking cold surfaces. Prior research showed there was less of a bouncing effect in such cases involving heated water droplets, with the droplets sticking to the surface instead thanks to various factors such as reduced droplet surface tension. The Hong Kong team discovered they could achieve enhanced bouncing by using hot droplets of less volatile liquids—namely, n-hexadecane, soybean oil, and silicon oil, which have lower saturation pressures compared to water.

Follow the bouncing droplet

The researchers tested these hot droplets (as well as burning and normal temperature droplets) on various solid, cold surfaces, including scratched glass, smooth glass, acrylic surfaces, surfaces with liquid-repellant coatings from candle soot, and surfaces coated with nanoparticles with varying "wettability" (i.e., how well particles stick to the surface). They captured the droplet behavior with both high-speed and thermal cameras, augmented with computer modeling.

The room-temperature droplets stuck to all the surfaces as expected, but the hot and burning droplets bounced. The team found that the bottom of a hot droplet cools faster than the top as it approaches a room-temperature surface, which causes hotter liquid within the droplet to flow from the edges toward the bottom. The air that is dragged to the bottom with it forms a thin cushion there and prevents the droplet from making contact with the surface, bouncing off instead. They dubbed the behavior "self-lubricated bouncing."

"It is now clear that droplet-bouncing strategies are not isolated to engineering the substrate and that the thermophysical properties of droplets themselves are critical," Jonathan B. Boreyko of Virginia Tech, who was not involved in the research, wrote in an accompanying commentary.

Future applications include improving the combustion efficiency of fuels or developing better fire-retardant coatings. "If burning droplets can't stick to surfaces, they won't be able to ignite new materials and allow fires to propagate," co-author Pingan Zhu said. "Our study could help protect flammable materials like textiles from burning droplets. Confining fires to a smaller area and slowing their spread could give firefighters more time to put them out."

DOI: Newton, 2025. 10.1016/j.newton.2025.100014  (About DOIs).